This will allow water movement over the total area of the sand, preventing accumulation of debris and allowing a larger surface area of sand to operate aerobically.
Algae (and the algae living inside the coral) give off oxygen, and use up CO2, when photosynthesising (when the lights are on) - this causes the water's pH to increase. During periods of darlness, they do just the reverse, causing the pH to drop.
"Reverse daylight" is just a term for running the sump lights "on" during the night, and "off" during the day. If you have a substantial amount of algae in the sump, you will find that doing so tends to smooth out the relatively large pH changes (of 0.3 - 0.5 pH...) normally found in a reef tank.
Hope this helps.
Hennie