Biological Cycling
When a marine aquarium is cycling focus on two primary objectives; discouraging harmful bacteria (heterotrophs), and encouraging beneficial bacteria (Nitrosomonas and Nitrobacter) - these are the starts.
Hetrotrophic bacteria decompose stray organic matter - this may seem good, but this matter is turned into toxic amonia NH3.
To prevent this do not overfeed, have a protein skimmer and a mechanical filtration method like a filter sock which must be cleaned every day.
Nitrosomonas found on well oxygenated substrate, rock and filters turn NH3 is turned into Nitrite. Bioballs will come in here.
Next Nitrobacter use oxygen and nitrite to convert it to Nitrate.
Now we need anaerobic bacteria (Nitrobacillus) to transport nitrogen out of the aquarium. They live in deep sand beds and porous rock where oxygen is low.
If your system does not display much sand or rock then bio balls will take that place inside your sump.
Take note that bacteria living on bioballs will die in the event of a power outage and not supplied with some sort of oxygen.