Effect of temperature
The light output and performance of fluorescent lamps is critically affected by the temperature of the bulb wall and its effect on the partial pressure of mercury vapor within the lamp.[6] Each lamp contains a small amount of mercury, which must vaporize to support the lamp current and generate light. At low temperatures the mercury is in the form of dispersed liquid droplets. As the lamp warms, more of the mercury is in vapor form. At higher temperatures, self-absorption in the vapor reduces the yield of UV and visible light. Since mercury condenses at the coolest spot in the lamp, careful design is required to maintain that spot at the optimum temperature, around 40 °C.
By using an amalgam with some other metal, the vapor pressure is reduced and the optimum temperature range extended upward; however, the bulb wall "cold spot" temperature must still be controlled to prevent migration of the mercury out of the amalgam and condensing on the cold spot. Fluorescent lamps intended for higher output will have structural features such as a deformed tube or internal heat-sinks to control cold spot temperature and mercury distribution. Heavily-loaded small lamps, such as compact fluorescent lamps, also include heat-sink areas in the tube to maintain mercury vapor pressure at the optimum value.[7]